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A rapeseed methyl ester biodiesel RMEB100 was tested on a heavy duty DI diesel engine under steady state conditions. The combustion performance and exhaust emissions were measured and compared to a standard petroleum derived diesel fuel. The engine used was a 6 cylinder, turbocharged, intercooled Perkins Phaser Engine, with emission compliance of EURO 2, fitted with an oxidation catalyst. The exhaust samples were taken both upstream and downstream of the catalyst. Particulates were collected and analysed for VOF, carbon and ash. A MEXA7100 gas analysis system was used for legislated gas analysis such as CO, CO2, NOx and total hydrocarbons. A FTIR analysis system was deployed for gaseous hydrocarbon speciation, which is capable of speciating up to 65 species. The results showed a significant reduction in total particulate mass, particulate VOF, CO, THC and aldehydes when using RMEB100.

Condensable and gaseous hydrocarbon emissions and speciation of the hydrocarbons have been investigated using a EURO1 emissions compliant SI (Spark Ignition) car. Exhaust gas samples were simultaneously collected upstream and downstream of the catalyst using a system containing cold ice trap, resin, particulate filter block and Teflon gas sampling bag. GC (Gas Chromatography) was employed to analyze for hydrocarbons and 16 of the more significant hydrocarbons are reported. The test was carried out using both cold start and hot start driving cycles. Results show that the benzene and toluene were major species emitted from the tailpipe under cold start conditions. Methylnaphthalene was a dominated hydrocarbon under hot start conditions. The cold start had significant influence on hydrocarbon emissions. The catalyst out benzene emissions for cold start was thirty times higher than that for hot start.

A series of chassis dynamometer test trials were conducted to assess the performance of a Fourier Transform Infra Red (FTIR) system developed for on-road vehicle exhaust emissions measurements. Trials used a EURO 1 emission compliant SI passenger car which, alongside the FTIR, was instrumented to allow the routine logging of engine speed, road speed, throttle position, air-fuel ratio, air flow and fuel flow in addition to engine, exhaust and catalyst temperatures. The chassis dynamometer facility incorporated an ‘industry standard’ measurement system comprising MEXA7400 gas analyzer and CVS bag sampling which was the ‘benchmark’ for the evaluation of FTIR legislated gas-phase emissions (CO, NOx, THC and CO2) measurements. Initial steady state measurements demonstrated strong correlations for CO, NOx and THC (R2 of 0.99, 0.97 0.99, respectively) and a good correlation for CO2 (R2 = 0.92).

A precision in-vehicle tail-pipe emission measurement system was installed in a EURO1 emissions compliant SI car and used to investigate the variability in tail-pipe emission generation at an urban traffic junction. Exhaust gas and skin temperatures were also measured along the exhaust pipe of the instrumented vehicle, so the thermal characteristics and the efficiency of the catalyst monitored could be included in the analysis. Different turning movements (driving patterns) at the priority T-junction were investigated such as straight, left and right turns with and without stops. The test car was hot stable running conditions before each test, thereby negating cold start effects. To demonstrate the influence of the junction on tail-pipe emissions and fuel consumption, distance based factors were determined that compared the intersection drive-through measurements with steady speed (state) runs. Fuel consumption was increased at intersections by a factor of 1.3∼5.9.

Thermal characteristics of SI engine exhaust during cold start and warm up period were investigated for different ambient temperatures (-2 to 32 °C). A Euro 1 emission compliance SI car was tested using a real world urban driving cycle to represent typical city driving patterns and simulate ECE15 urban driving cycle. The test car was equipped with 27 thermocouples along the engine and exhaust pipes so as to measure metal and exhaust gas temperatures along the engine, exhaust and catalyst. The characteristics of thermal properties of engine, exhaust system and catalyst were studied as a function of warm up time and ambient temperature. The temperature and time of the light-off of catalyst were investigated so as to evaluate the effect of thermal properties of the catalyst on emissions. The results show that the coolant water reached the full warm up about 5 minutes in summer and 9 minutes in winter after a cold start.

The objective of this work was the development of an on-road in-vehicle emissions measurement technique utilizing a relatively new, commercial, portable Fourier Transform Infra-Red (FTIR) Spectrometer capable of identifying and measuring (at approximately 3 second intervals) up to 51 different compounds. The FTIR was installed in a medium class EURO1 spark ignition passenger vehicle in order to measure on-road emissions. The vehicle was also instrumented to allow the logging of engine speed, road speed, global position, throttle position, air-fuel ratio, air flow and fuel flow in addition to engine, exhaust and catalyst temperatures. This instrumentation allowed the calculation of mass-based emissions from the volume-based concentrations measured by the FTIR. To validate the FTIR data, the instrument was used to measure emissions from an engine subjected to a real-world drive cycle using an AC dynamometer.

The influence of ambient temperature on exhaust emissions for an instrumented Euro 1 SI car was determined for urban congested traffic conditions. In UK cities cold-starting vehicles directly into congested traffic conditions is a common occurrence that is not currently taken into account when modeling urban traffic pollution. In-vehicle emission samples were taken directly from the exhaust, upstream and downstream of the catalyst, using the bag sampling technique. The first bag was for the cold start emissions and approximately the first 1.1 km of travel. The following three bags were with a hotter catalyst. The cold start tests were conducted over a year, with ambient temperatures ranging from 2°C to 30°C. The results showed that CO emissions for the cold start were reduced by 70% downstream of the catalyst when the ambient temperature rose from 2°C to 30°C. The corresponding hydrocarbon emissions were reduced by 41% and NOx emissions were increased by 90%.

Mass weighted size distributions of particulate emissions as a function of oil age were investigated using a set of Anderson Impactors on an IDI passenger car engine test. This engine was fitted with an on-line bypass lubricating oil recycler aiming to extend the oil life, reduce fuel consumption and exhaust emissions. A stop start test cycle was used with a cold start each time and a typical cycle period of 2∼3 hours. The whole test was carried out for nearly 500 hours. The first 310 hours of testing were with the oil recycler fitted and thereafter the test continued with the oil recycler disconnected. The results show that 60∼80% of mass particulates were smaller than 1.1 μm in aerodynamic diameter with the oil recycler fitted and this percentage was reduced to 40∼60% after disconnection of the oil recycler. The changes in size distribution with oil age mainly happened in the size ranges of 1.1∼0.65 μm, 0.65∼0.43 μm and <0.43 μm.

The influence of ambient temperature on exhaust emissions for an instrumented Euro 1 SI car was determined. A real world test cycle was used, based on an urban drive cycle that was similar to the ECE urban drive cycle. It was based on four laps of a street circuit and an emissions sample bag was taken for each lap. The bag for the first lap was for the cold start emissions. An in-vehicle direct exhaust dual bag sampling technique was used to simultaneously collect exhaust samples upstream and downstream of the three-way catalyst (TWC). The cold start tests were conducted over a year, with ambient temperatures ranging from - 2°C to 32°C. The exhaust system was instrumented with thermocouples so that the catalyst light off temperature could be determined. The results showed that CO emissions for the cold start were reduced by a factor of 8 downstream of catalyst when ambient temperature rose from -2°C to 32°C, the corresponding hydrocarbon emissions were reduced by a factor of 4.

An oxidation catalyst was fitted on a DI diesel engine for an experimental study involving an oxidation catalyst and the use of superheated steam for fumigating the intake air. Results are compared with that of the influence of low level of fumigation of the intake air with superheated diesel fuel. Exhaust emissions of NOx, CO, UHC, TPM, SOF and Carbon were measured and quantified on upstream and downstream of a low light off temperature (250 °C) oxidation catalyst. The technique used an electric vaporizer for producing superheated steam and prevaporised superheated diesel fumes at 350 °C, respectively. A low emissions version of Perkins 4-236 engine with squish lip piston was run both with and without fumigation at two speeds 1200 rpm and 2200 rpm. Roughly covering both city and highway running conditions.

Results showed the influence of the oxidation catalyst on exhaust emissions from a DI diesel engine due to the partial premixing, fumigation of the intake air with diesel fuel. Exhaust emissions of NOx, CO, UHC, TPM, SOF and Carbon were measured and quantified on upstream and downstream of a low light off temperature (250 °C) oxidation catalyst. Two methods of diesel fumigation of the intake air with fuel were used. The difference between these two methods was the degree of premixing of diesel fuel with the intake air. The first technique used a high-pressure fine diesel spray onto a glow plug and the second technique used an electric vaporizer for prevaporised superheated diesel fumes at 350 °C. A low emissions version of Perkins 4-236 engine with squish lip piston was run both with and without fumigation at two speeds 1200 rpm and 2200 rpm. Roughly covering both city and highway running conditions.

Results of an experimental study of a DI Diesel engine are presented, which show the influence of partial premixing fumigation of the intake air with diesel fuel on the exhaust emissions and the engine performance parameters. Exhaust emissions of NOx, CO, UHC, TPM, SOF and Carbon were measured and quantified. Engine performance parameters include the event of the start of combustion and fuel consumption besides other parameters, which were published elsewhere. The study also showed that during a “normal operation” of a DI diesel engine, no emissions trade-off exists between NOx and TPM. Rather these emissions need separate technological measures for their specific control. Two methods of diesel fumigation were used. The difference between these two methods was the degree of premixing of diesel fuel with the intake air.

Reduction of NOx was achieved in an experimental study in a DI Diesel engine. Results are presented, which show the comparison of the influence of partial fumigation of the intake air with superheated diesel fuel vapour and that of steam on the exhaust emissions and the engine performance parameters. Exhaust emissions of NOx, CO, UHC, TPM, SOF and Carbon were measured and quantified. The technique used for fumigating the intake air with fuel and steam consisted of an electric vaporizer for producing perfectly prevaporised superheated diesel fumes and steam at 350°C. A low emissions version of Perkins 4-236 engine with squish lip piston was run with the fumigation of the intake air with superheated fuel vapour and that of steam at two speeds 1200 rpm and 2200 rpm, roughly covering both city and highway running conditions.

This work is part of a larger programme to investigate the storage at low power conditions and release at high power conditions in real diesel engine exhaust systems. The initial particle storage in the oxidation catalyst, followed by a release of particles a few minutes later, is explored, and the associated particle size distribution changes determined. A Ford 1.8L IDI Diesel Engine, Turbocharged and Intercooled (TCIC), and equipped with Exhaust Gas Recirculation (EGR), was used under high speed and high power conditions, both during cold start. The commercial close-coupled diesel oxidation catalyst had an associated hydrocarbon adsorber for cold start hydrocarbon control. The tests were carried out using a step cold start to a fixed low power output, typical of city driving. The ELPI particle size analyser was used together with constant temperature gravimetric filter based mass samples upstream and downstream of the catalyst.

A method of cleaning lubricating oil on line was investigated using a fine bypass particulate filter followed by an infra red heater. Two bypass filter sizes of 6 and 1 micron were investigated, both filter sizes were effective but the one micron filter had the greatest benefit. This was tested on two nominally identical EURO 1 emissions compliance refuse trucks, fitted with Perkins Phazer 210Ti 6 litre turbocharged intercooled engines and coded as RT320 and RT321. These vehicles had lubricating oil deterioration and emissions characteristics that were significantly different, in spite of their similar age and total mileage. RT321 showed an apparent heavier black smoke than RT320. Comparison was made with the oil quality and fuel and lubricating oil consumption on the same vehicles and engines with and without the on-line bypass oil recycler. Engine oils were sampled and analysed about every 400 miles. Both vehicles started the test with an oil drain and fresh lubricating oil.

The accumulation and release of particulate matter within the exhaust system of a modern light-duty diesel engine was studied during a step cold start to three steady state load conditions, idle, 10 and 15kW. Changes in particulate mass concentration through the various components of the exhaust system were dependent on the previous short-term history of the engine operation, and on the engine speed reached during cold start. Particulate matter was deposited within the oxidation catalyst when cold and in the downstream exhaust silencer at idle and low power conditions. Particulate matter was released from the first silencer at all three test conditions and this release exceeded the deposition in the downstream silencer and resulted in a net exhaust system particulate blowout, at all three test conditions. This was a large fraction of the tailpipe emissions at all three test conditions.

A method of cleaning diesel engine lubricating oil on-line was investigated using a bypass fine particulate filter followed by an infra-red heater to remove water vapour and light diesel fractions in the oil. The impact of this oil recycler on the gaseous and particulate emissions was investigated over a 300 hour oil age period. A Ford 1.8 litre IDI passenger car diesel engine was used with engine out emission sampled every 15-20 hours. The tests were carried out at 2500rpm (52% of the maximum speed) and 12.3 kW with 47 Nm load (43% of the maximum load and 29% of the maximum power). The EGR level at this condition was 15%. A stop start test cycle was used with a cold start each time and a typical test period of 2-3 hours. The results showed that the recycler had its greatest influence on emissions for fresh oil when there was a large reduction in particulate emissions due mainly to large reductions in the ash, carbon and unburned lubricating oil fractions.

A method of cleaning lubricating oil on line was investigated using a fine bypass particulate filter followed by an infra red heater, to remove water and light diesel fractions in the oil. Two bypass filter sizes of 6 and 1 micron were investigated, both filter sizes were effective but the one micron filter had the greatest benefit. This was tested on two nominally identical Euro 2 emissions compliance single decker buses, fitted with Cummins 6 cylinder 8.3 litre turbocharged intercooled engines. These vehicles had oil deterioration and emissions characteristics that were significantly different, in spite of their similar age and total mileage. Comparison was made with the oil quality on the same vehicles and engines with and without the on-line recycler. Oil samples were analysed about every 2000 miles. All tests started with an oil drain and fresh lubricating oil.

Diesel exhaust particle size distribution and total number concentration were measured at different positions along the exhaust system of a practical light-duty passenger car diesel engine. Continuous particle size measurements during the diesel cold start were made in 12 particle size ranges using the ELPI particle size analyser. Three engine speeds were studied using a step cold start procedure to the set load and speed condition. The exhaust system had an oxidation catalyst with hydrocarbon absorber and two silencers. Particle size distributions were determined upstream and downstream of the catalyst and the two silencers. There were considerable variations in the particle number and size distribution after the cold start. The catalyst was shown to act as a store for fine particles and there were further particle losses across the two silencers.

SYNOPSIS A method of cleaning the oil on line was investigated using a bypass fine particulate filter followed by an infra red heater to remove water and light diesel fractions in the oil. This was tested on a range of on road vehicles and a Ford 1.8 litre IDI passenger car engine on a test bed. Comparison was made with the oil quality on the same vehicles and engines without the on-line recycler. Test times were from 200 to 1500 hours of oil ageing and some of the tests showed that the oil quality was still good after 4 times the normal oil life. The results showed that the on line oil recycler cleaning system reduced the rate of fall of the TBN and rate of increase of the TAN. There was a very significant reduction in the soot in oil and the fuel dilution. There was also a consistent reduction in all the wear metals apart from copper and a decrease in the rate of reduction of oil additives. There was also measured on the Ford IDI engine a 5% reduced fuel consumption.